*  Exposure Controls/Personal Protection  *
Respiratory Protection:ALL RESPS MUST BE NIOSH/MSHA APPRVD.WHERE
    ADEQUATE VENTILATION NOT AVAIL & USE GENERATES VAPOR OR FUMES, USE
    ACID-GAS RESPS W/DUST, MIST & FUME FILTERS. UNDER CNDTNS
    NECESSITATING HIGHER LEVEL OF PROT , USE POSITIVE PRESS,
    AIR-SUPPLIED RESP.
Ventilation:LOCAL EXHAUST VENTILATION, ENCLOSED SYSTEM DESIGN OR
    PROCESS ISOLATION & REMOTE CONTROL.
Other Protective Equipment:EYE WASH FOUNTAINS & SAFETY SHOWERS.
    IMPERVIOUS CLOTHING AND FOOTWEAR SELECTED WITH REGARD FOR CONDITION
    EXPOSURE.
Work Hygienic Practices:ALL FOOD MUST BE KEPT  FROM STOR/USE LOCATION.
    EATING, DRINKING, SMOKING & CARRYING OF TOBACCO PRODS MUST BE (ING
Supplemental Safety and Health
EXPLO HAZ:PROD FROM BROKEN CNTNRS INCR CONTAM OR FIRE HAZ. DO NOT GET
    WATER INSIDE CNTNRS AS VIGOROUS RXN MAY RSLT, GENERATING HIGH TEMPS
    & PRESSURES. OTHER PREC:MAINTAINED. IT IS STRONGLY RECOMMENDED 
    POINT) PRIOR TO INTRODUCTION OF TITANIUM TETRACHLORIDE.
*  Product Identification  *
Product ID:TITANIUM TETRACHLORIDE
Preparer's Name:PRODUCT STEWARDSHIP
*  Composition/Information on Ingredients  *
Ingred Name:HYGIENE PRACT:PREVENTED IN AREAS WHERE THERE IS POTNTL FOR
Ingred Name:TITANIUM TETRACHLORIDE (TICL*4);(TITANIUM TETRACHLORIDE)
    (SARA III)
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:FIRST AID PROC:AFFECTED AREAS THORO W/LRG AMTS OF RUNNING
Ingred Name:ING 2:W/CHEMICAL AGENTS. GET MD IMMED. DISCARD CONTAM CLTHG
    & SHOES. EYE:IMMED FLUSH W/LRG QTYS OF RUNNING WATER (ING 4)
    FLUSHING TO ENSURE RINSING OF ENTIRE SURF OF EYE & LIDS(ING 5)
Ingred Name:ING 4:W/WATER. DO NOT ATTEMPT TO NEUTRALIZE W/CHEM AGENTS.
    GET MD IMMED. OILS OR OINTMENTS SHOULD NOT BE USED (ING 6)
    IF MD NOT IMMED AVAIL. INHAL:MOVE TO FRESH AIR. IF NOT (ING 7)
Ingred Name:ING 6:BRTHG, CLEAR VICTIMS AIRWAY & START MOUTH-TO-MOUTH
    ARTF RESP, WHICH MAY BE SUPPLEMENTED BY USE OF BAG-MASK (ING 8)
Ingred Name:ING 7:RESP OR MANUALLY TRIGGERED O*2 SUPPLY CAPABLE OF
    DELIVERING ONE LITER PER SECOND OR MORE. IF VICTIM (ING 9)
Ingred Name:ING 8:BRTHG, SUPPLEMENTAL O*2 MAY BE GIVEN FROM DEMAND-TYPE
    OR CONTINUOUS FLOW INHALER,PREF W/MD'S ADVICE. GET MD IMMED.
Ingred Name:SPILL PROC:STIFF BRUSH, WORK SLURRY INTO CRACKS/CREVICES.
    ALLOW TO STAND FOR 2-3 MINS THEN FLUSH W/WATER. REPEAT IF NEC.
*  Hazards Identification  *
Routes of Entry: Inhalation:YES  Skin:NO  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CONTACT WITH SKIN OR EYES MAY PRODUCE
    SEVERE IRRITATION OR BURNS. INHALATION OF TITANIUM TETRACHLORIDE OR
    FUMES MAY PRODUCE SEVERE IRRITATION TO THE UPPER RESPIRATORY TRACT
    WITH COUGHING, BURNING OF T HE THROAT, HEADACHE, DIZZINESS &
    WEAKNESS. LUNG DAMAGE, PULMONARY EDEMA AND EVEN DEATH. BRONCHIAL
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:PNEUMONIA MAY RESULT FROM PROLONGED OR
    REPEATED EXPOSURES TO LOW CONCENTRATIONS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
*  First Aid Measures  *
First Aid:INGEST:IMMED GIVE SEVERAL GLASSES OF WATER, BUT DO NOT INDUCE
    VOMIT. MATL IS CORROSIVE. IF VOMIT OCCURS, GIVE FLUIDS AGAIN. HAVE
    MD DETERMINE IF CNDTN OF PATIENT WILL PERMIT INDUCTION OF VOMIT OR
    EVAC UATION OF STOMACH. DO NOT GIVE ANYTHINGBY MOUTH TO UNCON/CONVL
    PERS. SKIN:USING DRY CLOTH, WIPE AWAY EXCESS MATL FROM SKIN &
    REMOVE ALL CONTAM CLTHG & SHOES. UNDER SAFETY SHOWER FLUSH ALL (ING
    2)
*  Fire Fighting Measures  *
Extinguishing Media:SMALL FIRES:USE DRY CHEMICAL OR CO*2. LARGE
    FIRES:FLOOD W/WATER, COPIOUS QUANTITIES ARE REQUIRED TO SCRUB
    LIBERATED HCL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
    PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:IF NOT LEAKING, KEEP FIRE EXPOSED CNTNRS
    COOL W/WATER SPRAY TO PVNT RUPTURE DUE TO EXCESS HEAT. DO NOT USE
    HIGH PRESS WATER HOSE AS IT MAY SPREAD (SUPP DATA)
*  Accidental Release Measures  *
Spill Release Procedures:SOAK UP POOLED LIQ W/SUITABLE ABSORBENT SUCH
    AS CLAY, SAWDUST OR KITTY LITTER. SWEEP UP ABSORBED MATL & PLACE IN
    CHEM WASTE CNTNR FOR DISP. GENEROUSLY COVER CONTAM AREA W/SLURRY OF
    COMMON HOUSEHOLD, P OWDERED LAUNDRY DETERGENT & WATER. USING (ING
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage  *
Handling and Storage Precautions:CNTNRS SHOULD BE STORED IN COOL, DRY,
    WELL VENT AREA AWAY FROM FLAMM MATLS & SOURCES OF HEAT OR FLAME.
    STORE AWAY FROM FOODSTUFFS AND ANIMAL FEED.
Other Precautions:EXERCISE DUE CAUTION TO PREVENT DAMAGE TO OR LEAKAGE
    FROM CNTNR. CNTNRS SHOULD ONLY BE OPENED IN DRY, O*2 FREE INERT
    ATMOSPHERE. CARBON STEEL IS PREF MATL OF CONSTRUCTION FOR STOR
    CNTNRS BUT ONLY IF C OMPLETELY ANHYDROUS CNDTNS (SUPP DATA)
*  Physical/Chemical Properties  *
Solubility in Water:HYDROLYZES IN WATER
Appearance and Odor:COLORLESS LIQUID WITH IRRITATING ODOR
*  Stability and Reactivity Data  *
Stability Indicator/Materials to Avoid:YES
REACTS VIOLENTLY WITH WATER PRODUCING HCL, TIO*X, TITANIUM OXYCHLORIDE
    & HEAT. BY FIRE:HCL & CL*2 GAS.
Stability Condition to Avoid:MOIST AIR.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
*  Disposal Considerations  *
Waste Disposal Methods:MATERIAL THAT CANNOT BE USED OR CHEMICALLY
    PROCESSED AND EMPTY CONTAINERS MUST BE DISPOSED OF ACCORDING TO ANY
    APPLICABLE REGULATIONS. NOTE:DISPOSAL MUST BE IN ACCORDANCE WITH
    LOCAL, STATE AND FEDERAL  REGULATIONS .
