*  Exposure Controls/Personal Protection  *
Respiratory Protection:AVOID BRTHG VAP &/OR DUST. USE NIOSH APPRVD RESP
    PROT EQUIP (FULL FACEPIECE RECOMMENDED) WHEN AIRBORNE EXPOS IS
    EXCESS. CONSULT RESP MANUFACTURER TO DETERMINE APPROPRIATE TYPE
    EQUIP FOR GIVEN APPLICAT ION. OBSERVE RESP USE LIMITATIONS
    SPECIFIED BY NIOSH/MANUFACTURER. RESP PROT PROGRAMS MUST COMPLY
Ventilation:PROVIDE NATURAL/MECHANICAL VENT TO MINIMIZE EXPOSURE. IF
    PRACTICAL, USE LOCAL MECH EXHAUST VENT AT SOURCES OF AIR
    CONTAMINATION SUCH AS OPEN PROCESS EQUIP.
Other Protective Equipment:EYEWASH & DELUGE SHOWER MTG ANSI DESIGN
    CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. WASH
    CONTAMINATED SKIN PROMPTLY. LAUNDER CONTAMINATED CLOTHING AND CLEAN
    PROTECTIVE EQUIPMENT BEFORE REUSE.
Supplemental Safety and Health
SPILL PROC: BURN CONTAINERS IN APPROVED INCINERATOR/DISPOSE OF IN
    CHEMICAL LANDFILL WHICH COMPLIES W/ALL APPLIC LOCAL, STATE &
    FEDERAL LAWS & REGS. FOR EMERGENCY ASSISTANCE (ONLY IN EVENT OF
    CHEM EMER GENCIES INVOLVING SPILL, LEAK, EXPOS/ACCIDENT INVOLVING
*  Product Identification  *
Product ID:SANTOGARD PVI PREVULCANIZATION INHIBITOR
*  Composition/Information on Ingredients  *
Ingred Name:N-(CYCLOHEXYLTHIO) PHTHALIMIDE
Other REC Limits:N/K 
OSHA PEL:N/K 
OSHA STEL:N/K 
ACGIH TLV:N/K 
ACGIH STEL:N/K 
Ingred Name:BUTYL OLEATE. PRESENT ONLY IN SANTOGARD PVI-DS.
= Wt:1.
Other REC Limits:N/K 
OSHA PEL:N/K 
OSHA STEL:N/K 
ACGIH TLV:N/K 
ACGIH STEL:N/K 
*  Hazards Identification  *
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:NO
Reports of Carcinogenicity:NTP:NO    IARC:NOOSHA:NO
Health Hazards Acute and Chronic:THE FOLLOWING INFORMATION SUMMARIZES
    HUMAN EXPERIENCE AND RESULTS OF SCIENTIFIC INVESTIGATIONS REVIEWED
    BY HEALTH PROFESSIONALS FOR HAZARD EVALUATION OF SANTOGARD PVI
    PREVULCANIZATION INHIBITOR AND DE VELOPMENT OF PRECAUTIONARY
    STATEMENTS AND OCCUPATIONAL CONTROL PROCEDURES RECOMMENDED IN THIS
    DOCUMENT. SKIN CONTACT AND INHALATION ARE EXPECTED TO BE THE
    PRIMARY ROUTES OF OCCUPATIONAL EXPOSURE TO SA NTOGARD PVI
    PREVULCANIZATION INHIBITOR. OCCUPATIONAL EXPOSURE TO THIS MATERIAL
    HAS BEEN REPORTED TO CAUSE EYE AND SKIN IRRITATION. (EFFECTS OF
    OVEREXPOSURE)
Effects of Overexposure:HEALTH HAZARDS: IN ADDITION, THIS MATERIAL MAY
    PRODUCE ALLERGIC SKIN REACTION IN SUSCEPTIBLE INDIVIDUALS.
    FOLLOWING EXPOSURE TO SANTOGARD PVI, WORKERS HAVE REPORTED THE
    PRESENCE OF A STRONG ODOR (MERC APTAN-LIKE) ON THE SKIN WHICH CAN
    BE REMOVED BY PERSPIRATION, WASHING OR SHOWERING. SOME EXPOSED
    INDIVIDUALS HAVE REPORTED NAUSEA DUE TO THIS STRONG ODOR.
*  First Aid Measures  *
    MINUTES. GET MEDICAL ATTENTION. SKIN: IMMEDIATELY WASH WITH SOAP
    AND PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
    ATTENTION.WASH CLOTHING BEFORE REUSE. INHALATION: REMOVE PERSON
    TO FRESH AIR. REMOVE MATERIAL FROM EYES, SKIN AND CLOTHING.
    INGESTION: CALL MD IMMEDIATELY .
*  Fire Fighting Measures  *
Flash Point Method:PMCC
Extinguishing Media:WATER SPRAY OR OTHER CLASS A EXTINGUISHING AGENT.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
    APPARATUS AND FULL PROTECTIVE EQUIPMENT . THOROUGHLY DECONTAMINATE
    EQUIPMENT AFTER USE.
Unusual Fire/Explosion Hazard:CARBON MONOXIDE, SULFUR DIOXIDE &
    NITROGEN OXIDE ARE EMITTED WHEN PROD IS IGNITED. NOTE: PROD IS
    SOMETIMES SOLD AS MILLED GRADE. THIS FINE PARTICLE SIZE CREATES
    POTENTIAL FOR DUST EXPLO/FIRES. FOR ANY  OPERATIONS INVOLVING
    MILLED PROD/ANY ADDN TO FLAMM SOLVS, USE ONLY ELEC EQUIP THAT IS
    SUITABLE FOR HAZ (OTHER INFO)
*  Accidental Release Measures  *
Spill Release Procedures:AVOID CREATING DUST CLOUD AS THIS MATL, IF
    DISPERSED IN AIR, COULD PRESENT POTENTIAL DUST EXPLO HAZ. DO NOT
    BLOW MATL. USE VACUUM EQUIP DESIGNED SPECIFICALLY FOR HNDLG COMBUST
    DUSTS. VACUUM/SWEEP UP &  PLACE IN DRY, COVERED, CLEAN CONTR. WEAR
    MATL OUT OF SEWERS, WATERSHEDS & WATERWAYS. (SUP DAT)
*Handling and Storage  *
Handling and Storage Precautions:DURING STOR AVOID EXTREMES OF TEMPS &
    HUMIDITY. SUGGESTED MAX STOR TIME IS ONE YEAR. COMBUST DUST - EXPLO
    POTENTIAL. KEEP AWAY FROM HEAT, SPARKS & FLAME. AVOID CREATING DUST
    IN HNDLG, TRANSFER/CLEAN U P. AVOID CONT W/EYES, SKIN & CLOTHING.
    AVOID BREATHING VAP/DUST. KEEP CONTR CLOSED. USE W/ADEQ VENT.
Other Precautions:EMPTIED CONTR RETAINS VAP & PROD RESIDUE. OBSERVE ALL
    LABELED SAFEGUARDS UNTIL CONTR IS CLEANED, RECONDITIONED/DESTROYED.
    STORE IN COOL DRY PLACE, AWAY FROM FOODSTUFFS & ACIDS. FOR ADDNL
    PROD INFO, IN CL PROD FORMS, CHARACTS & APPLICATIONS, & FDA REGS,
    CONSULT MONSANTO RUBBER CHEMICALS PURCHASING GUI DE.
*  Physical/Chemical Properties  *
Solubility in Water:INSOLUBLE
Appearance and Odor:LIGHT TAN TO WHITE CRYSTALS; SLIGHT MERCAPTAN ODOR.
*  Stability and Reactivity Data  *
Stability Indicator/Materials to Avoid:YES
ACIDS.
Hazardous Decomposition Products:IF STRONGLY HEATED, THIS PRODUCT MAY
    CATCH FIRE AND GIVE OFF TOXIC FUMES OF CARBON MONOXIDE, SULFUR
    DIOXIDE AND NITROGEN OXIDES.
*  Toxicological Information*
Toxicological Information:DATA FROM AVAIL SCIENTIFIC LITERATURE ARE
    GIVEN BELOW: SINGLE-DOSE (ACUTE) STUDIES INDICATE: ORAL: SLIGHTLY
    TESTED FOR POTENTIAL TO PRDCE ALLERGIC SKIN RXN IN CONTROLLED SKIN
    CONT STUDIES W/HUMAN VOLUNTEERS. P OTENTIAL FOR PRIMARY &
    CUMULATIVE IRRIT WAS DEMONSTRATED & ALLERGIC SKIN RXN WAS OBSERVED.
    THIS MATL, WHEN PRESENT AT 2 PHR IN RUBBER STOCK, WAS ONLY A
    CUMULATIVE SKIN IRRITANT IN HUMAN VOLUNTEERS. (T RANSPORT INFO)
*  Ecological Information  *
    W/ TRANSFERRING PROD,  GROUND EQUIP, PROV INERT ATM & PROP
    DESIGNING MATL HNDLG EQUIP, TO PVNT ELECTROSTATIC CHARGE.
    (PHYS/CHEM PROPERTIES): NOTE:  PHYS DATA ARE TYP VALUES BSD ON MATL
    TESTED BUT MAY VARY. TYP VALUES SHD NOT BE CONSTRUED AS GUARAN
    ANALYSIS OF ANY SPECIFIC LOT. MFR INTERNAL EXP LIMIT: 0.5 MG/M3, 8
    HR TWA, SKIN ABS MAY ADD TO THE  OVERALL EXP. AVOID SKIN CONTACT.
*  Disposal Considerations  *
Waste Disposal Methods:WHEN DISCARDED, MATL IS NOT "HAZ WASTE" AS THAT
    HAZ WASTE". BURN IN APPRVD INCIN/DISPOSE OF IN APPRVD CHEM LANDFILL
    WHICH COMPLIES W/A LL APPLIC LOC, STATE & FED LAWS & REGS. CONSULT
    YOUR ATTORNEY/APPROP REGULATORY OFFICIALS FOR INFO O N SUCH DISP.
*  MSDS Transport Information  *
Transport Information:DOT PROPER SHIPPING NAME: ORM-A, N.O.S. (VIA
    N/A. U.S. SURF FREIGHT CLASSIFICATION: RUBBER PRESERVATIVES,
    N.O.I.B.N. TOX INFO: NO ADVER SE EFTS WERE OBSERVED IN RATS EXPOSED
    PROD DUST, RATS SHOWED INCRD KIDNEY WTS & DMG, & LUNG EFTS. THIS
    MATL GIVEN TO RATS IN THEIR D IETS FOR 4 WKS PRDCED ONLY DECRD BODY
    WTS. PROD GIVEN TO RATS BY DIETARY ADMIN WAS SHOWN TO ENHANCE
    CARCIN ACTIVITY OF DIETHYLNITROSAMINE, A KNOWN CARCIN. (SARA REGS)
*  Regulatory Information  *
SARA Title III Information:HAZARD CATEGORIES UNDER CRITERIA OF SARA
    DECREASED BODY WTS, SERUM CHEMISTRY CHANGES, BLOOD CHANGES,
    INCREASED KIDNEY & LIVER WTS AS WELL AS CHANGES IN THESE ORGANS.
    DOSE-RELATED INCR IN BENIGN LIVER TUMORS WA S ALSO OBSERVED IN
    FEMALE RATS. A MULTIGENERATIONAL STUDY W/RATS GIVEN PROD IN THEIR
    DIETS REPORTED DECREASED BODY WTS IN FIRTS GENERATION RATS &
    INCREASE IN MORTALITY IN OFFSPRINGS OF SECOND GENERATI ON. (STATE
    REGS)
Federal Regulatory Information:EPA REG NUMBER: NOT APPLICABLE. TSCA
    INVENTORY: THIS PRODUCT APPEARS ON THE INVENTORY OF CHEMICAL
    SUBSTANCES PUBLISHED BY THE U.S. ENVIRONMENTAL PROTECTION AGENCY
    (EPA) UNDER THE AUTHORITY OF THE TOXI C SUBSTANCES CONTROL ACT
    REGULATIONS: NOT APPLICABLE. HAZARDOUS CHEMICAL(S) UNDER OSHA
    HAZARD COMMUNICATION STANDARD: THIS CHEMICAL IS ID ENTIFIED AS A
    HAZARDOUS CHEMICAL UNDER THE CRITERIA OF THE OSHA HAZARD
State Regulatory Information:SARA REGS: HOWEVER, NO CONSISTENT ADVERSE
    REPRODUCTIVE EFFECTS WERE OBSERVED IN THIS STUDY. NO BIRTH DEFECTS
    WERE OBSERVED IN RABBITS GIVEN THIS MATERIAL ORALLY DURING
    PREGNANCY, EVEN AT LEVELS WHICH  PRODUCED TOXIC EFFECTS IN THE
    MOTHERS AND OFFSPRINGS. NO ADVERSE GENETIC CHANGES WERE OBSERVED IN
    STANDARD TESTS USING BACTERIAL AND ANIMAL CELLS AND ANIMALS.
*  Other Information  *
