*  Exposure Controls/Personal Protection  *
Respiratory Protection:AIRLINE RESPIRATORS UNLESS AIR SAMPLING SHOWS
    EXPOSURE TO BE BELOW OSHA LIMITS. THEN, EITHER CHEMICAL CARTRIDGE
    RESPIRATORS OR AIRLINE RESPIRATORS ARE REQUIRED.USE SAME
    PRECAUTIONS DURING MIXING OR WH ERE PAINT FUMES WOULD BE PRESENT.
*  Product Identification  *
Preparer's Name:JANE FREEMAN
*  Composition/Information on Ingredients  *
Ingred Name:METHYL ISOBUTYL KETONE
Ingred Name:SILICA, CRYSTALLINE
Other REC Limits:NONE
OSHA PEL:0.1 MG/M3
ACGIH TLV:0.1 MG/M3
Ingred Name:XYLENE  (SARA III)
Ingred Name:BUTYL ACETATE  (SARA III)
Ingred Name:HEXAMETHYLENE DIISOCYANATE MONOMER
Other REC Limits:NONE
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:HOMOPOLYMER OF HEXAMETHYLENE DIISOCYANATE
Other REC Limits:TWA=0.5MG/M3(MFR)
Ingred Name:METHYL ISOAMYL KETONE
Ingred Name:BLACK IRON OXIDE PIGMENT
Other REC Limits:LIMITS/IRON OXID FUM
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3
Ingred Name:IRON OXIDE YELLOW
Fraction by Wt: 1-5%
Other REC Limits:FOR IRON OXIDE FUME
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3
*  Hazards Identification  *
Reports of Carcinogenicity:NTP:YES    IARC:YES
Health Hazards Acute and
    Chronic:ACUTE:EYES:IRRIT/TEARING/REDDENING/SWELLING/STINGING.IF
    UNTREATED:CORNEAL DAMAGE/SLOW TO
    HEAL.SKIN:IRRIT:REDDENING/RASH/SWELLING/SCALING/BLISTERING/POSSIBLE
    SKIN SENSITIZATION.IF MATERIAL DRIES ON SKI N:REMOVAL VERY
    DIFFICULT.REPEATED/PROLONGED SKIN CONTACT:POSSIBLE
    DEFATTING/DERMATITIS.INHAL:ANESTHETIC.POSSIBLE RESP TRACT
    IRRIT/ACUTE NERVOUS SYSTEM DEPRESSION SHOWN BY
    HEADACHE/DIZZINESS/STAGGERING
    /CONFUSION/UNCONSCIOUSNESS.ISOCYANATES IRRIT/BURN MUCOUS MEMBRANE
    IN RESP TRACT(NOSE/THROAT/LUNGS):RUNNY NOSE/SOAR
    THROAT/COUGHING/CHEST DISCOMFORT/SHORTENED BREATH/REDUCED LUNG
    FUNCTION/BREATHING OBS TRUCTION.*CONTINUED UNDER SIGNS/SYMPTOMS
Explanation of Carcinogenicity:IARCH LISTS CRYSTALINE SILICA:GROUP
    1,CARCENOGENIC TO HUMANS.NTP CLASSIFIES CRYSTALINE SILICA AS
    REASONABLY ANTICIPATED TO BE CARCINOGEN:MAY CAUSE LUNG INJURY IF
    RESP PRECAUTIONS ARE NOT USED.
Effects of Overexposure:CONTINUED HEALTH HAZ:INHAL:POSSIBLE ASTHMA-LIKE
    SYMPTOMS/ASTHMA ATTACK.POSSIBLE BRONCITIS/BRONCHIAL SPASM/PULMONARY
    EDEMA.THESE EFFECTS USUALLY REVERSABLE.POSSIBLE CHEMICAL
    PNEUMONITIS W/FLU-LIKE SYMP TOMS(FEVER/CHILLS).POSSIBLE THROAT
    DRYNESS/CHEST TIGHTNESS/HEADACHE/NAUSEA/FATIGUE/APPETITE
    LOSS.INGEST:IRRIT/POSSIBLE CORROSIVE ACTION:MOUTH/STOMACH
    TISSUE/DIGEST TRACT.SYMPTOMS:SOAR THROAT/ABDOMONAL 
    PAIN/NAUSEA/VOMITING/DIARRHEA.VOMITING CAUSE POSSIBLE ASPIRATION OF
    SOLVENT INTO LUNGS LEADING TO CHEMICAL PNEUMONITITS. **CONTINUED
    UNDER TOXICOLOGICAL SECTION (SIGN&SYMPTOMS LISTED BELOW UNDER MED 
    COND AGGRAVATED)
Medical Cond Aggravated by Exposure:ASTHMA/OTHER RESP AILMENTS.SKIN
    ALERGIES/EXEMA.CHEM SENSTZATION.SIGNS&SYMPTOMS:HARMFUL IF
    INHALED.EFFECTS:NOSE,THROAT,RESP TRACT IRRIT,ALERGIC RESP
    REACTION,LUNG DAMAGE,EYE&SKIN IRRIT,SKIN REACTIONS.
*  First Aid Measures  *
    MINUTES, LIFTING LIDS TO RINSE ENTIRE EYE. TAKE TO DR IMMED.SKIN:
    REMOVE CONTAMINATED CLOTHING IMMED & WASH THOROUGHLY BEFORE REUSE.
    WASH EFFEC TED AREAS THOROUGHLY W/SOAP/WATER. SEVERE EXPOSURE:GET
    UNDER SAFETY SHOWER AFTER REMOVING CLOTHING. CALL DR IN BOTH
    CASES.INHAL:REMOVE TO RISK FREE AREA.ADMINISTER OXYGEN/ARTIFICIAL
    RESP AS NEEDED. GE T DR. POSSIBLE ASTHMIATIC TYPE SYMPTOMS IMMED OR
    SEVERAL HOURS LATER. SEE DR. INGEST:CALL DR IMMED! DO NOT INDUCE
    VOMITING.
*  Fire Fighting Measures  *
Lower Limits:1.0
Extinguishing Media:FOAM, DRY CHEMICAL AND CO2 OR ALCOHOL FOAM
Fire Fighting Procedures:FULL PROTECT EQUIP W/ SELF-CONTAINED BREATHING
    APPARATUS SHOULD BE WORN.DURING FIRE, IRRIT & HIGHLY TOXIC GASES &
    SMOKE ARE PRESENT FROM DECOMP/COMBUST PRODS.KEEP CONTRS TIGHTLY
    CLOSED.ISOLATE FROM HE AT/ELECTRICAL EQUIP/SPARKS/OPEN FLAMES.
Unusual Fire/Explosion Hazard:CLOSED CONTRS MAY EXPLODE WHEN EXPOSED TO
    EXTREME HEAT OR BURST WHEN CONTAM W/ H2O (CO2 RELEASED).DO NOT
    APPLY TO HOT SURFACES.NEVER USE WELDING/CUTTING TORCH ON/NEAR
    CONTRS(EVEN EMPTY) B/C PRODUCT(EV EN RESIDUE) CAN IGNITE
    EXPLOSIVELY.FLAMMABLE LIQUID!KEEP AWAY FROM
    HEAT/SPARKS/FLAME.VAPORS MAY CAUSE FLASH FIRE.
*  Accidental Release Measures  *
Spill Release Procedures:EVAC NON-ESSENTIAL PERSONNEL.REMOVE ALL IGNIT
    SOURCES:FLAMES/HOT SURFACES/ELECTRICAL/STATIC & FRICTIONAL
    SPARKS.VENTILATE AREA.EQUIP CLEAN UP CREW W/APRROP PROTECTIVE
    EQUIP.AVOID BREATH VAPORS/SKIN CO NTACT.COVER SPILL W/INERT
    MATERIAL IN OPEN CONTNRS/ADD FURTHER AMOUNTS DECONTAM
    SOLUTION.***CONT UNDER ECOLOGICAL SECTION
*Handling and Storage  *
Handling and Storage Precautions:PROTECT PERSONS HANDLING PRODUCT:MUST
    NOT BREATHE VAPORS/CONTACT EYES/SKIN. IN SPRAY
    OPERATIONS:PROTECTION AFFORDED AGAINST EXPOSURE TO VAPOR/SPRAY
    MIST.CAN CAUSE IRRIT TO EYES/SKIN/NOSE/THROAT.AVOID  EYES/CLOTHING
    CONTACT.WASH THOROUGHLY AFTER HANDLING. AVOID PROLONGED/REPEATED
    CONTACT W/SKIN.
Other Precautions:USE GROUNDING/BONDING CONNECTIONS IN TRANFERING
    MATERIAL TO PREVENT STATIC DISCHARGE/FIRE OR EXPLOSION.AVOID LIQUID
    FREE-FALL>FEW INCHES.USE SPARK PROOF TOOLS/EXPLOSION PROOF
    ECOLOGICAL
    *****CONTINUED UNDER OTHER INFORMATION SECTION
Ventilation:EXHAUST TO KEEP AIRBORN CONTAMS BELOW EXPOSURE LIMITS.CLEAN
    EXHAUST AIR BY SCRUBBER/FILTERS.VENT CURING OVENS.IF OVEN OFF,GASES
    NOT VENTED PROPERLY
    SHIELD.NO CONTACT LENSES.
Other Protective Equipment:WEAR PROTECTIVE CLOTHING TO KEEP SKIN
    CONTACT AT A MINIMUM.KEEP SKIN CREAM PROTECTED AREAS TO A
    MINIMUM.SAFETY SHOWERS/EYE WASH STATIONS.TRAIN EMPLOYEES IN SAFE
    USE OF THIS PRODUCT.
Work Hygienic Practices:ONCE A PERSON IS SENSITIZED TO ISOCYANATES, NO
    FURTHER EXPOSURE CAN BE PERMITTED.
Supplemental Safety and Health
MEDICAL SUPERVISION OF ALL EMPLOYEES HANDLING THIS PRODUCT
    RECOMMENDED.SHOULD INCLUDE PRE-EMPLOYMENT & PERIODIC MEDICAL EXAMS
    W/ RESP FUNCTION TESTS(FEV, FVC MINIMUM).PERSONS W/ASTHMA-TYPE
    CONDITIONS/ BRONCHITIS/OTHER RESP DISEASES OR RECURRENT SKIN
    EXEMA/SENSITIZATION SHOULD BE EXCLUDED FROM WORKING W/ISOCYANATES.
*  Physical/Chemical Properties  *
Solubility in Water:REACTS WITH WATER
Appearance and Odor:OPAQUE LIQUID, SOLVENT ODOR
*  Stability and Reactivity Data  *
Stability Indicator/Materials to Avoid:YES
WATER/MOISTURE,EPOXY CATALYSTS,ALCOHOLS,GLYCOL ETHERS,BASES,METAL
    COMPLEXES,OR OTHER ACTIVE MATERIALS.
Stability Condition to Avoid:ONCE PRODUCT IS EXPOSED TO ANY MATERIALS
    LISTED BELOW (INCLUD ATMOSPHERIC MOISTURE), DO NOT RESEAL CONTR AS
    HAZ CO2 GAS COULD BUILD UP IN CONTR RESULTING IN RAPID
    DEPRESSURIZATION.
Hazardous Decomposition Products:MAY PRODUCE HAZ FUMES WHEN HEATED TO
    DECOMP POINT(AS IN WELDING). FUMES MAY CONTAIN:CO2, CO,
    CHLORINE,HYDROGEN CHLORIDE & POSSIBLE CYANIDE, HEXAMETHYLENE
    DIISOCYANATE.
*  Toxicological Information*
Toxicological Information:*CONT HEALTH HAZ CHRONIC EFFECTS:POSSIBLE
    PERMANENT BRAIN,NERVOUS SYSTEM,LUNG,LIVER&KIDNEY DAMAGE.CERTAIN
    PERSONS DEVELOP ISOCYANATE SENSITIZATION(CHEMICAL ASTHMA)CAUSING
    REACTIONS TO LATER EXPOSURE W ELL<TLV.SYMPTOMS IMMED OR DELAYED UP
    TO SEVERAL HOURS AFTER EXPSRE.INCLUDES:CHEST
    TIGHTNESS,WHEEZING,COUGH,ASTHMATIC ATTACK.ONCE SENSITIZED,PERSON
    CAN HAVE THESE SYMPTOMS EXPOSED TO DUST/COLD AIR/OTHE R
    IRRITANTS.CAN PERSIST FOR WEEKS/SOME CASES-SEVERAL
    YEARS.SENSIZATION TEMP OR PERMANENT.POSSIBLE SKIN
    REDDENING,SWELLING,DERMATITIS.REPORTS LINK XYLENE TO HEARING LOSS.
*  Ecological Information  *
Ecological:***CONT SPILL RELEASE:REMOVE CONTRS TO SAFE PLACE.COVER
    SOLUTION.DON'T ALLOW PRODUCT/USED DECONTAM SOLUTION TO ENTER
    DRAINS,SEWERS,WATERWAYS . ****CONT STORAGE&HANDLING:KEEP AWAY FRM
    HEAT/SPARKS/FLAME.KEEP CONTRS TIGHTLY CLOSED&PROTECT FRM MOISTURE
    CONTAMINATION.IF MOISTURE ENTERS CONTR,PRESSURE CAN BUILD DUE TO
    REACTION PRODUCING CO2, WHI CH CAUSES SEALED CONTR TO
    PRESSURIZE&BURST.DON'T RESEAL CONTR IF CONTAM IS SUSPECTED.EMPTY
    CONTRS RETAIN HAZ RESIDUE.FOLLOW HAZ PRECAUTIONS UNTIL CONTR
    THOROUGHLY CLEANED/DESTROYED.SOAK SOILED RAGS&WA STE IMMED IN
    H2OFILLED CLOSED CONTR.
*  Disposal Considerations  *
Waste Disposal Methods:RECYCLE,FUEL BLEND,OR INCINERATE.DISPOSE OF IN
    ACCORDANCE W/ LOCAL/STATE/FED ENVIRONMENTAL CONTROL
    REGULATIONS.DISPOSE OF PROPERLY.PROFILE WASTE W/ LAB ANALYSIS FOR
    PROPER DISPOSAL. DECONTAMINATE CONT AINERS W/ DECONTAM SOLUTION. US
*  MSDS Transport Information  *
Transport Information:*******CONTINUED FROM STATE REG SECTION:USE ONE
    OR MORE OF FOLLOWING CONTROL PROCEDURES WHEN WELDING/CUTTING COATED
    STEEL:USE POWER BRUSH,GRINDING WHEEL,OR CHEM STRIPPER TO REMOVE
    COATING FROM STEEL I N THE AREA TO BE CUT OR WELDED.USE RESP/EYE
    PROTECTION WHILE STRIPPING PAINT.USE LOCAL EXHAUST HOOD TO REMOVE
    FUMES DURING WELDING/CUTTING OPERATION.WEAR A FRESH AIR SUPPLIED
    RESPIRATOR DURING WELDING /CUTTING.
*  Regulatory Information  *
SARA Title III Information:HEXAMETHYLENE DIISOCYANATE MONOMER; XYLENE;
    METHYL ISOBUTYL KETONE.
Federal Regulatory Information:CONT RESPIRATORY: A PROPERLY FITTED AIR
    PURIFYING RESP(COMBO ORGANIC VAPOR/PARTICULATE), PROVEN BY TESTS TO
    BE EFFECTIVE IN ISOCYANATE-CONTAINING SPRAY PAINT ENVIRONMENTS AND
    USED IN ACCORD W/ ALL REC OMMENDATIONS MADE BY MANUFACTURER CAN BE
    USED WHEN:1)AIRBORNE ISOCYANATE CONCENTRATIONS ARE KNOWN TO BE
    BELOW TEN TIMES EXPOSURE LIMITS;2)AT LEAST ONE SOLVENT IN COATING
    HAS PUBLISHED ODOR THRESHHOLD; AND 3)AIRBORNE SOLVENT IS LOWER THAN
    ITS TLV BUT HIGHER THAN ITS ODOR THRESHHOLD.ODOR OF SOLVENT WIL L
    THEN ALERT RESP WEARER TO ANY BREAKDOWN OF RESP FILTERS. CONT UNDER
    STATE REG. SECTION
State Regulatory Information:CONT FROM FED REGS:SAME PRECAUTIONS APPLY
    DURING NONSPRAY OPERATIONS SUCH AS BRUSH,ROLLER APPLICATION OF
    COATING IF DONE AT ELEVATED TEMPS(HEATING COATING FOR
    APPLICATION).DURING SANDING/GRINDING USIN G NIOSH APPROVED
    PARTICULATE RESP TO REMOVE SOLID AIRBORNE PARTICLES OF DUST. WHEN
    WELLDING/CUTTING STEEL COATED W/PRODUCT, WORKER MAY BE EXPOSED TO
    DECOMP PRODUCTS(METAL FUMES,GASES,VAPORS,AND/OR PAR TICULATE)WHICH
    VARY DEPENDING ON TYPE OF PROCESS BEING USED TO WELD/CUT AND NATURE
    OF BASE METAL. ** ****CONTINUED UNDER TRANSPORTATION SECTION.
*  Other Information  *
 *
