*  Exposure Controls/Personal Protection  *
Respiratory Protection:USE NIOSH/MSHA APPRVD AIR-SUPPLIED RESPS FOR
    SCBA IN POS PRESS DEMAND MODE IS REQD FOR HIGHER CONCS. RESP PROT
Ventilation:EXPLO-PROOF LOC EXHST VENT SYS W/SUFFICIENT AIR FLOW
Other Protective Equipment:METATARSAL SHOES FOR CYL HNDLG. PROT CLTHG.
    FOUNTAINS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SPILL PROC:AREA. PVNT RUN-OFF FROM CONTAM SURROUND ENVIRON. WASTE DISP
    METH:QTYS OF SODIUM/CALCIUM HYPOCHLORITE, POTASSIUM PERMANGANATE,
    BROMINE WATER/SODIUM HYPOBROMITE SOLN. FIRE FIGHT PROC:EXTING F
    LAMES. SOLID STREAMS OF WATER MAY BE INEFT. REMOVE IGNIT SOURCES IF
    W/OUT RISK. IF FLAMES ARE ACCIDENTALLY (ING 2)
*  Product Identification  *
Product ID:PHOSPHINE
*  Composition/Information on Ingredients  *
    DISTRIBUTION SYS & CONTINUOUS GAS MONITORS IS REC.
Ingred Name:VENT:ZONE. MECH(GEN):NOT REC AS PRIMARY VENT SYS TO CONTROL
    APPROP FOR CERTAIN APPLICATIONS.
Ingred Name:PHOSPHINE  (SARA III)
OSHA PEL:0.3 PPM;1 PPM STEL
ACGIH TLV:0.3 PPM;1 PPM STEL
Ingred Name:SUPDAT:EXTING, EXPLO RE-IGNIT MAY OCCUR; THEREFORE APPROP
    MEASURES SHOULD BE TAKEN; E.G., TOTAL EVACUATION TO (ING 3)
Ingred Name:ING 2:PROT PERS FROM CYL FRAGMENTS & TOX FUMES SHOULD
    RUPTURE OCCUR. REAPPROACH W/EXTREME CAUT. REDUCE TOX VAPS (ING 4)
Ingred Name:ING 3:W/WATER SPRAY/FOG. STOP FLOW OF GAS IF W/OUT RISK.
    ALLOW FIRE TO BURN OUT. ONSITE FIRE BRIGADES MUST (ING 5)
Ingred Name:EXPLO HAZ:CYL MAY RUPTURE DUE TO HEAT OF FIRE. DO NOT
    EXTING FLAMES DUE TO POSS OF EXPLO RE-IGNIT. FLAMM & TOX (ING 7)
Ingred Name:ING 6:VAPS MAY SPREAD FROM SPILL. EXPLO ATMS MAY LINGER.
    BEFORE ENTERING AREA, ESP CONFINED AREAS, CHECK ATM W/ (ING 8)
Ingred Name:ING 7:APPROP DEVICE. NO PART OF CNTNR SHOULD BE SUBJECTED
Ingred Name:ING 8:DEVICE TO RELEASE PRESSURE.
    OPHTHALMOLOGIST, URGENTLY. NOTE TO MD:ING 1 IS SEV PULM IRRIT.(ING
    DIRECTED AT CONTROL OF SYMPS & CLINICAL CNDTNS OF PATIENT.
Ingred Name:OTHER PREC:WHEN RETURNING CYL, INSTALL VALVE OUTLET PLUG
*  Hazards Identification  *
Routes of Entry: Inhalation:YES  Skin:NO  Ingestion:NO
Reports of Carcinogenicity:NTP:NO    IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INGEST:FROSTBT OF LIPS & MOUTH
    MAY RSLT FROM CONT W/LIQ. INHAL:HIGHLY TOX. MAY BE FATAL. EFTS INCL
    IRRIT OF RESP TRACT & LUNGS, CHEST PAIN, DFCLTY IN BRTHG, FATG,
    HDCH, ABDOM PAIN, NAUS, VOMIT,  DIARR, DROW, DIZZ, STAG, CONVLS &
    COLLAPSE. INTERVAL BTWN ONSET OF EXPOS & SYMPS IS DEPENDENT ON CONC
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:OF GAS & DURATION OF EXPOS. SYMPS CAN
    CHRONIC:WHEN INHALED, ING 1 RELS INORG PHOSPHORUS. RPTD OVEREXP TO
    PHOSPHORUS CAN RSLT IN A NEMIA, BRONCH, GI DISTURBS. MAY CAUSE
    KIDNEY, LIVER, HEART DMG. CNS DEPRESS & CARDIAC ARRHYTHMIA MAY ALSO
    OCCUR.
Medical Cond Aggravated by Exposure:BREATHING OF VAP/MIST MAY AGGRAVATE
    ASTHMA & INFLAMMATORY OR FIBROTIC PULMONARY DISEASE. INDIVIDUALS
    W/PRE-EXISTING KIDNEY, HEART, LIVER OR NERVOUS SYSTEM DISEASE MAY
    BE AT INCREASED RISK.
*  First Aid Measures  *
First Aid:INGEST:CALL MD IMMED. SKIN:IMMED WARM FROSTBT AREA W/WARM
    W/WARM WATER. CALL MED ATTN IMMED. INHAL:IMMED REMOVE TO FRESH AIR.
    GIVE  ARTF RESP IF NOT BRTHG. OXYGEN MAY BE GIVEN BY QUALIFIED PERS
    IF BRTHG IS DFCLT. GET MED ATTN IMMED, EVEN IF NO SYMPS ARE
    PRESENT. EYE:IMMED FLUSH THORO W/WATER & CONTINUE FLUSHING FOR AT
*  Fire Fighting Measures  *
Flash Point:FLAMMABLE GAS
Extinguishing Media:CO*2, DRY CHEMICAL, WATER SPRAY OR FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
    EVACUATE ALL PERS FROM DANGER AREA. IMMED COOL CNTNRS W/WATER SPRAY
    FROM MAX DIST TAKING CARE NOT TO(SUPDAT)
Unusual Fire/Explosion Hazard:POIS, FLAMM GAS. MAY FORM EXPLO MIXTS
    W/AIR & OXIDIZING AGENTS. ING 1 MAY SPONT IGNITE IN CONT W/AIR.
    BECAUSE CYL VALVE IS NOT EQUIPPED W/SFTY DEVICE, (ING 6)
*  Accidental Release Measures  *
Spill Release Procedures:IMMED EVACUATE ALL PERS FROM DANGER AREA. USE
    NIOSH/MSHA APPRVD SCBA WHERE NEEDED. REMOVE ALL SOURCES OF IGNIT IF
    W/OUT RISK. REDUCE VAPS W/FOG/FINE WATER SPRAY. SHUT OFF LEAK IF
    W/OUT RISK. VENT AREA  OF LEAK/MOVE LEAKING CNTNR TO
    WELL-VENTED(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage  *
Handling and Storage Precautions:POIS, FLAMM, LIQUEFIED GAS UNDER
    PRESS. DO NOT BREATHE GAS. DO NOT GET LIQ/VAPS IN EYES, ON
    SKIN/CLTHG. GROUND ALL EQUIP. USE ONLY IN CLSD SYS.
Other Precautions:USE PIPING & EQUIP ADEQ DESIGNED TO W/STAND PRESS TO
    BE ENCOUNTERED. KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. USE
    SPK-PROOF TOOLS & EXPLO-PROOF EQUIP. STORE & USE W/ADEQ VENT AT ALL
*  Physical/Chemical Properties  *
HCC:G8
Solubility in Water:SLIGHT
Appearance and Odor:COLORLESS GAS AT NORMAL TEMPERATURE & PRESSURE;
    ODOR OF DECAYING FISH.
*  Stability and Reactivity Data  *
Stability Indicator/Materials to Avoid:YES
HALOGENATED HYDROCARBONS, OXIDIZING AGENTS, ESP OXYGEN & HALOGENS,
    ACIDS, AS WELL AS ALUMINUM ALLOYS & COPPER.
Stability Condition to Avoid:DECOMPOSES AT TEMPERATURES IN EXCESS OF
Hazardous Decomposition Products:THERMAL DECOMPOSITION OR BURNING MAY
    PRODUCE HYDROGEN, PHOSPHORUS, PHOSPHORUS OXIDES.
*  Disposal Considerations  *
Waste Disposal Methods:PVNT WASTE FROM CONTAM SURROUND ENVIRON. KEEP
    PERS AWAY. DISCARD ANY PROD, RESIDUE, DISP CNTNR/LINER IN ENVIRON
    ACCEPT MANNER, IN FULL COMPLIANCE W/FED, STATE & LOC REGS. ING 1
    CAN BE DISP OF BY SLOWL Y INTRODUCING GAS INTO DISP SYS CNTNG
    ADEQ(SUPDAT)
