*  Exposure Controls/Personal Protection  *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATORY PROTECTION IN
    ABSENCE OF PROPER ENVIRONMENTAL CONTROL. FOR EMERGENCIES, A
    NIOSH/MSHA APPROVED SELF CONTAINED BREATHING APPARATUS OR A
    NIOSH/MSHA APPROVED FULL FACE RESP IRATOR IS RECOMMENDED.
Ventilation:SUFFICIENT TO PREVENT VAPOR CONTACT. RECOMMEND CONTROL OF
    VAPORS TO SUGGESTED GUIDE. LOCAL EXHAUST.
Other Protective Equipment:EYE FOUNTAIN AND SAFETY SHOWER. CLEAN,
    BODY-COVERING CLOTHING, BOOTS, AND APRON.
Work Hygienic Practices:USE GOOD INDUSTRIAL HYGIENE.
Supplemental Safety and Health
FIRST AID PROC: TO MED FACILITY. DESTROY CONTAMD SHOES. WASH CLTHG
    BEFORE REUSE. INHAL: REMOVE TO FRESH AIR IF EFTS OCCUR. CALL PHYS
    &/OR TRANSPORT TO MED FACILITY. ADMIN OXYGEN IF AVAIL. BRONCHODIALA
    TORS, EXPECTORANTS, & ANTITUSSIVES MAY BE OF HELP. INGEST: MOD TOX.
    MAY CAUSE BURN OF MUC MEMBS. IF LAVAGE IS (ING 3)
*  Product Identification  *
Preparer's Name:GEORGE C. KARPIN
    INC.
*  Composition/Information on Ingredients  *
Ingred Name:SUPP DATA:PERFORMED, SUGGEST ENDOTRACHEAL &/OR
    ESOPHAGOSCOPIC CNTRL. RECOM TO PHYS: SYS: CONSULT STD LITERATURE.
    (ING 4)
Ingred Name:ING 3: NO SPECIFIC ANTIDOTE. TREATMENT BASED ON SOUND
    JUDGMENT AND INDIVIDUAL REACTIONS OF PATIENT.
Ingred Name:DIETHYLENE TRIAMINE
OSHA PEL:1 PPM
ACGIH TLV:1 PPM, S
Ingred Name:ANILINE, 4,4'-METHYLENEDI-; (4,4'-METHYLENEDIANILINE) (MDA)
ACGIH TLV:0.1 PPM, S
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
*  Hazards Identification  *
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:YES    IARC:YES  OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:MAY CAUSE ALLERGENIC
    ASTHMA.MAY CAUSE SEV IRRIT.MAY CAUSE RESP SENSIT/ASTHMA. INGEST:LOW
    SINGLE DOSE ORAL TOX;INGEST MAY CAUSE BURNS OF MOUTH, ESOPHAGUS &
    POSS STOM.MAY CAUSE BURNS OF MUC  MEMB.EYE:MAY CAUSE SERIOUS BURN
    W/POSS LOSS OF VISION.MAY CAUSE SEV CORNEAL INJ/BURN. SKIN: BRIEF
    CONT (EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE DIANILINE (4,4): GROUP 2B
    (IARC), ANTICIPATED TO BE A CARCINOGEN (NTP).
Effects of Overexposure:HLTH HAZ:(3-5 MINS) MAY CAUSE SERIOUS BURN.
    MATL MAY CAUSE SIGNIFICANT SENSIT/ALLERGENIC RESPONSE. SKIN ABSORP:
    MAY BE ABSORB IN MOD TOX AMTS. CHRONIC: HUMAN LIVER TOX. FEVER,
    CHILLS, ANOREXIA (ANXIET Y) & VOMIT. TOX HEPATITIS, JAUNDICE,
    HEPATOTOXIN EFTS. PRODCES ANEMIA & LIVER, THYROID & KIDNEY TOX IN
    LAB TEST ANIMALS.
Medical Cond Aggravated by Exposure:EXISTING LIVER DISORDERS MAY BE
    AGGRAVATED BY PRODUCT. ALSO EXISTING LUNG DISORDERS. IRRITATION OF
    EYES, NOSE, THROAT AND LUNGS. MAY CAUSE SENSITIZATION BY LIQUID OR
    VAPORS.
*  First Aid Measures  *
First Aid:EYE:IMMED & CONTINUOUS IRRIGATION W/FLOWING WATER FOR AT LST
    STAIN FOR EVIDENCE OF CORNEAL INJ. IF CORNEA IS BURNED, INSTILL
    ANTIBIOTICSTEROID PREPARATION FREQUENTLY. CONSULTOPHTHALMOLOGIST.
    IS INDICATED. REMOVE CONTAMD CLTHG IMMED. CALL PHYS &/OR TRANSPORT
    (SUPDAT)
*  Fire Fighting Measures  *
Flash Point Method:PMCC
Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
    PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
*  Accidental Release Measures  *
Spill Release Procedures:CONSULT SPECIAL HANDLING INFO FOR PROPER
    PROTECTIVE EQUIPMENT. LARGE SPILL-DIKE UP AND DILUTE WITH COPIOUS
    QUANTITIES OF WATER. PUMP INTO APPROPRIATE CONTAINERS. SMALL
    SPILL-SOAK UP MATERIAL WITH ABSO RBENT MATL; SHOVEL INTO APPROP
    CONTAINERS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage  *
Handling and Storage Precautions:MATERIAL SHOULD NOT COME IN CONTACT
    WITH COPPER OR COPPER BEARING ALLOYS.
Other Precautions:NONE. MATERIAL MAY PRESENT A DUST HAZARD IF CUT,
    GROUND, OR MACHINED AFTER CURING.
*  Physical/Chemical Properties  *
HCC:C2
Solubility in Water:SLIGHT
Appearance and Odor:DARK BROWN LIQUID, AMINE ODOR.
Percent Volatiles by Volume:NIL
*  Stability and Reactivity Data  *
Stability Indicator/Materials to Avoid:YES
ACID, OXIDIZING MATERIAL, CHLORINATED ORGANIC COMPOUNDS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:NITROGEN OXIDES WHEN BURNED.
*  Disposal Considerations  *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
    AND FEDERAL REGULATIONS. KEEP OUT OF PUBLIC WATER SUPPLIES.
