Control Measures 
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Product ID: CITRIC ACID, ANHYDROUS
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Contractor Summary 
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Item Description Information 
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Item Manager: S9G
Item Name: CITRIC ACID,ANHYDROUS,TECHNICAL
Unit of Issue: BT
UI Container Qty: 1
Type of Container: BOTTLE
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Ingredients 
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Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
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Health Hazards Data 
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: MODERATELY IRRITATING TO SKIN AND SEVERELY IRRITATING TO
  THE EYES. INHALATION MAY CAUSE MINOR RESPIRATORY TRACT IRRITATION &
  COUGH. INGESTION OF LARGE QUANTITIES MAY RESULT IN HYPOCALCEMIA (CALCIUM DE
  FICIENDY IN BLOOD). CHRONIC OR HEAVY ACUTE INGESTION MAY CAUSE TOOTH ENAMEL
  EROSION.
Explanation Of Carcinogenicity: THIS COMPOUND CONTAINS NO INGREDIENTS AT
  CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
  CARCINOGENS.
Signs And Symptions Of Overexposure: SKIN IRRITATION, EYE IRRITATION,
  CONJUNCTIVAL ULCERATION OF CORNEA, RESPIRATORY TRACT IRRITATON, COUGH,
  CALCIUM DEFICIENCY IN BLOOD, TOOTH EROSION.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
  GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP
  & WATER. IF IRRITATION PERSIST, GET MEDICAL ATTENTION. INHAL ATION:
  REMOVE TO FRESH AIR. RESTORE BREATHING. GET MEDICAL ATTENTION. INGESTION:
  NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. CONTACT POISON CONTROL CENTER.
  DRINK 1-2 GLASSES OF WATER, INDUCE VOMITING
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Handling and Disposal
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Spill Release Procedures: ISOLATE AND VENTILATE AREA. SHUT OFF ALL IGNITION
  SOURCES. CLEANUP PERSONNEL SHOULD PROTECT AGAINST DUST INHALATION &
  SKIN/EYE CONTACT. DO NOT SWEEP UP. WET DOWN AND SCOOP INTO SUITABLE
  CONTAINERS.
Neutralizing Agent: LIME CAN BE ADDED TO NEUTRALIZE & PRECIPITATE CALCIUM
  CITRATE FROM SOLUTION.
Waste Disposal Methods: PREVENT WASTE FROM CONTAMINATING SURROUNDING
  ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR LINER IN
  ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
Handling And Storage Precautions: PREVENT PHYSICAL DAMAGE TO CONTAINERS. STORE
  IN COOL, DRY, WELL-VENTILATED AREA AWAY FROM HEAT, IGNITION SOURCES AND
  INCOMPATIBLES.
Other Precautions: DO NOT STORE IN CONTAINERS MADE OF COPPER, ALUMINUM OR THEIR
  ALLOYS. CONSIDER PREPLACEMENT AND PERIODIC MEDICAL EXAMS OF EXPOSED WORKERS.
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Fire and Explosion Hazard Information 
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Flash Point Text: COMBUSTIBLESOLID
Extinguishing Media: FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER SPRAY
Fire Fighting Procedures: FIRE FIGHTERS SHOULD WEAR SELF CONTAINED BREATHING
  APPARATUS AND FULL PROTECTIVE GEAR. COOL TANKS AND CONTAINERS EXPOSED TO FIRE
  WITH WATER.
Unusual Fire/Explosion Hazard: WHEN IN FINELY DIVIDED POWDER FORM, CITRIC ACID
  IS AN EXPLOSION HAZARD. THE UPPER AND LOWER AIR EXPLOSION LIMIT VALUES ARE
  FOR DUST IN AIR.
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Respiratory Protection: THE USE OF A DUST MASK SHOULD BE SUFFICIENT FOR
  PROTECTION AGAINST INHALATION OF CITRIC ACID PARTICULATES. IF RESPIRATORS ARE
  USED, OSHA REQUIRES A WRITTEN RESPIRATORY PROTECTION PROGRAM.
Ventilation: EXHAUST VENTILATION SUFFICIENT TO KEEP AIRBORNE CONCENTRATIONS
  BELOW RESPECTIVE TLV'S.
Other Protective Equipment: CHEMICAL RESISTANT CLOTHING AS NECESSARY TO PREVENT
  SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE AVAILABLE.
Work Hygienic Practices: WASH HANDS THOROUGHLY WITH SOAP AND WATER BEFORE
  EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health: REMOVE AND WASH CONTAMINATED CLOTHING BEFORE
  REUSE.
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Physical/Chemical Properties 
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HCC: C3
B.P. Text: DECOMPOSES
Decomp Text: NOT GIVEN
Vapor Pres: NEGLIGIBLE
Vapor Density: NOT GIVEN
PH: ACIDIC
Viscosity: NOT GIVEN
Evaporation Rate & Reference: NOT GIVEN
Solubility in Water: APPRECIABLE
Appearance and Odor: ODORLESS, COLORLESS, TRANSLUCENT CRYSTALS OR WHITE
  GRANULES, STRONG ACID TASTE
Corrosion Rate: UNKNOWN
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Reactivity Data 
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Stability Indicator: YES
Stability Condition To Avoid: DISPERSING POWDER IN AIR, CONTACT WITH
  INCOMPATIBLES, EXPOSURE TO HEAT & IGNITION SOURCES.
Materials To Avoid: POTASSIUM TARTRATE, ALKALI & ALKALINE EARTH CARBONATES &
  BICARBONATES, ACETATES, SULFITES, METAL NITRATES.
Hazardous Decomposition Products: ACRID IRRITATING SMOKE
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: ANHYDROUS CITRIC ACID READILY ABSORBS
  MOISTURE FROM AIR. DILUTE AQUEOUS SOLTUION MAY FERMENT TO OXALIC ACID.
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Toxicological Information 
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Ecological Information 
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Regulatory Information 
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Other Information 
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Transportation Information 
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Product ID: CITRIC ACID, ANHYDROUS
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: BT
Container QTY: 1
Type Of Container: BOTTLE
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Detail DOT Information 
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DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail IMO Information 
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IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
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Detail IATA Information 
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IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail AFI Information 
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AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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HAZCOM Label 
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Product ID: CITRIC ACID, ANHYDROUS
Company Name: LOS ANGELES CHEMICAL CO
Label Required IND: Y
Status Code: C
MFG Label NO: NONE
Origination Code: F
Skin Protection IND: YES
Signal Word: CAUTION
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: Slight
Hazard And Precautions: PREVENT PHYSICAL DAMAGE TO CONTAINERS. STORE IN COOL,
  DRY, WELL-VENTILATED AREA AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLES.
  GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP
  & WATER. IF IRRITATION PERSIST, GET MEDICAL ATTENTION. INHALATION: REMOVE
  TO FRESH AIR. RESTORE BREATHING. GET MEDICA L ATTENTION. INGESTION: NEVER
  GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. CONTACT POISON CONTROL CENTER. DRINK
  1-2 GLASSES OF WATER, INDUCE VOMITING.
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