Control Measures 
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Box: 9
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Contractor Summary 
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Item Description Information 
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Ingredients 
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% low Wt: 1.
% high Wt: 5.
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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% low Wt: 1.
% high Wt: 5.
OSHA PEL: 3 MG/M3
ACGIH TLV: 3 MG/M3
ACGIH STEL: NOT ESTABLISHED
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% low Wt: 1.
% high Wt: 5.
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ACGIH STEL: NOT ESTABLISHED
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% low Wt: .1
% high Wt: 1.
OSHA PEL: see Table Z-3
ACGIH TLV: 0.1 MG/M3
ACGIH STEL: NOT ESTABLISHED
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Health Hazards Data 
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: INGEST: HARMFUL IF SWALLOWED. EYE CONT: CAUSES
  IRRIT. SKIN CONT: MAY CAUSE SLIGHT IRRIT. INHAL: VAP AND/OR SPRAY MIST MAY BE
  HARMFUL IF INHALED. SIGNS & SYMPS OF OVEREXPOS: REDNESS, ITCHING, BU
  RNING SENSATION & VISUAL DISTURB MAY INDICATE EXCESS EYE CONT. DRYNESS,
  ITCHING, CRACKING, BURNING, REDNESS, & SWELL ARE CNDTNS ASSOC W/ EXCESS
  SKIN CONT. CHRONIC: AVOID LONG-TERM & RPTD CONT. PROD CN TNS CRYSTALLINE
  SILICA WHICH HAS BEEN CLASSIFIED AS HUMAN CARCIN BY IARC. LONG-TERM EXPOS MAY
  ALSO LEAD TO DISABLING LUNG CNDTNS KNOWN AS SILICOSIS. RISK DEPENDS ON
  DURATION & LEVEL OF EXPOS TO DUST F ROM SANDING SURF/ MIST (EFTS OF
  OVEREXP)
Explanation Of Carcinogenicity: SILICA, CRYSTALLINE-QUARTZ: IARC MONOGRAPHS,
  TO BE CARCINOGEN.
Signs And Symptions Of Overexposure: HLTH HAZS: FROM SPRAY APPLIC. USE OF
  APPROP PERSONAL PROT EQUIP AND/OR ENGINEERING CTLS SHOULD BE EMPLOYED
  WHENEVER THESE TYPES OF OPERATIONS ARE BEING PERFORMED. INGEST OF PRODS CNTNG
  ETHYLENE GLYCOL  MAY DMG KIDNEYS & LIVER & HAS BEEN SHOWN TO CAUSE
  BIRTH DEFECTS IN LAB ANIMALS. NO EVID OF THESE EFTS HAS BEEN FOUND IN HUMANS.
  THIS PROD CNTNS TITANIUM DIOXIDE. ANIMALS INHALING MASSIVE QTYS OF TITA NIUM
  DIOXIDE DUST IN LONG-TERM STUDY DEVELOPED LUNG TUMORS. STUDIES W/HUMANS
  INVOLVED IN MFR OF THIS PIGMENT INDICATE NO INCR RISK OF CANCER FROM
  EXPOSURE. POTNTL FOR INHAL OF (SUPDAT)
First Aid: INGEST: DO NOT INDUCE VOMIT. GENTLY WIPE OUT INSIDE MOUTH TO REMOVE
  ANY RESIDUAL MATL. EYE CONT: REMOVE CONT LENSES & FLUSH IMMED W/GENTLE
  INHAL: REMOVE TO FRESH AIR. APPLY ARTF RESP & OTHER SUPPORT MEASURES AS
  REQD. OTHER: IF INGEST, ANY TYPE OF OVEREXP/SYM PS OF OVEREXP OCCUR DURING OR
  FOLLOWING USE OF THIS PROD, CONT POIS CTL CTR, EMER ROOM/PHYS IMMED; HAVE
  MSDS INFORMATION AVAILABLE.
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Handling and Disposal
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Spill Release Procedures: PROVIDE MAX VENT. ONLY PERSONNEL EQUIPPED W/PROPER
  NIOSH APPROVED RESPIRATORY, SKIN, & EYE PROT SHOULD BE PERMITTED IN AREA.
  REMOVE ALL SOURCES OF IGNIT. TAKE UP SPILLED MATL W/SAND, VERMICULITE/OTHER 
  NONCOMBUST ABSORB MATL & PLACE IN CLEAN, EMPTY CNTNRS FOR DISP. ONLY
  SPILLED MATL & ABSORB SHOULD BE PLACE IN THIS CONTAINER.
Waste Disposal Methods: WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE WITH
  FEDERAL, STATE, PROVINCIAL, AND LOCAL ENVIRONMENTAL CONTROL REGS. EMPTY
  CNTNRS SHOULD BE RECYCLED OR DISPOSED OF THROUGH AN APPROVED WASTE MANAGEM
  ENT FACILITY.
  C).
Other Precautions: VAPORS MAY COLLECT IN LOW AREAS. IF THIS MATL IS PART OF A
  MULTIPLE COMPONENT SYSTEM, READ MSDS(S) FOR OTHER COMPONENT/COMPONENTS BEFORE
  BLENDING AS RESULTING MIXTURE MAY HAVE HAZARDS OF ALL OF ITS PA RTS.
  CONTAINERS SHOULD BE GROUNDED WHEN POURING. AVOID FREE FALL OF LIQUIDS IN
  EXCESS OF FEW INCHES.
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Fire and Explosion Hazard Information 
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Extinguishing Media: USE EXTINGUISHERS APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures: WEAR NIOSH APPRVD SCBA & FULL PROTECTIVE
  EQUIPMENT (FP N). WATER SPRAY MAY BE INEFTIVE. WATER SPRAY MAY BE USED TO
  COOL CLSD CNTNRS TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN
  EXPOSED TO EXTREM E HEAT. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE.
Unusual Fire/Explosion Hazard: KEEP PROD AWAY FROM HEAT, SPKS, FLAME, &
  OTHER SOURCES OF IGNIT(I.E., PILOT LIGHTS, ELEC MOTORS, STATIC ELECTRICITY).
  INVISIBLE VAPS CAN TRAVEL TO SOURCE OF IGNIT & FLASH BACK. DO NOT SMOKE
  WHILE USIN G PROD. KEEP CNTNRS TIGHTLY CLSD WHEN NOT IN USE. CLSD CNTNRS MAY
  EXPLODE WHEN OVERHEATED. DO NOT APPLY TO HOT (SUPDAT)
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Respiratory Protection: WHERE VENT IS INADEQ, USE NIOSH APPRVD AIR PURIFYING
  RESP W/APPROP CHEM CARTRIDGES OR POSITIVE-PRESS, AIR-SUPPLIED RESP. READ RESP
  MFR'S INSTRUCTIONS & LITERATURE CAREFULLY TO DETERM TYPE OF AIRBORNE 
  CONTAMINANTS AGAINST WHICH RESP IS EFTIVE, ITS LIMITATIONS, AND HOW IT IS TO
  BE PROPERLY FITTED & USED.
Ventilation: PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO KEEP
  CONC OF INGREDS LISTED BELOW LOWEST SUGGESTED EXPOS LIMITS, LEL BELOW STATED
  LIMIT, (SUPDAT)
Other Protective Equipment: NIOSH APPRVD EYE WASH & DELUGE SHOWER (FP N). WEAR
  PROT CLTHG. NO SPECIFIC PERMEATION/DEGRADATION TESTING HAVE BEEN DONE ON PROT
  CLTHG/THIS PROD. REC FOR SKIN PROT ARE BASED ON INFREQUENT (OTHER INFO)
Work Hygienic Practices: CLEAN CONTAMINATED CLOTHING AND SHOES.
Supplemental Safety and Health: SIGNS & SYMPS OF OVEREXP: TITANIUM DIOXIDE
  DUSTS FROM COATINGS IS VERY LIMITED. SINCE OVEREXP ARE NOT EXPECTED, THERE IS
  NO SIGNIFICANT HAZ FOR MAN. EXPLO HAZS: SURFS. TOXIC GASES MAY FORM WHEN PROD
  C OMES IN CONT W/EXTREME HEAT. VENT: & TO REMOVE DECOMP PRODS DURING
  WELDING/FLAME CUTTING.
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Physical/Chemical Properties 
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Vapor Density: HVR/AIR
Appearance and Odor: VISCOUS LIQUID WITH ODOR CHARACTERISTIC OF THE SOLVENTS
  LISTED IN INGREDIENTS.
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Reactivity Data 
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Stability Indicator: YES
Stability Condition To Avoid: AVOID CONTACT WITH STRONG ALKALIES, STRONG
  MINERAL ACIDS, OR STRONG OXIDIZING AGENTS.
Materials To Avoid: AVOID CONTACT WITH STRONG ALKALIES, STRONG MINERAL ACIDS,
  OR STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: MAY PRDCE FOLLOWING HAZ DECOMP PRODS WHEN
  EXPOS TO EXTREME HEAT; OXIDES OF ALUMINUM; OXIDES OF ZINC; CO, CO*2; LOWER
  MOLECULAR WT POLYMER FRACTIONS; EXTREME HEAT INCL, BUT IS NOT LIMITED
  TO,(OTHER INFO)
Hazardous Polymerization Indicator: NO
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Toxicological Information 
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Ecological Information 
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Transport Information: PRODUCT STATUS RELATIVE TO THE U.S. EPA TOXIC SUBSTANCES
  CONTROL ACT. ALL CHEMICAL SUBSTANES IN THIS PRODUCT ARE LISTED ON THE U.S.
  TSCA INVENTORY OR ARE OTHERWISE EXEMPT FROM TSCA INVENTORY REPORTING 
  REQUIREMENTS.
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Regulatory Information 
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  CATEGORIES FOR THIS PROD: ACUTE = Y, CHRONIC =Y, FLAMMABILITY = N, PRESSURE
  =N, REACTIVITY =N. THIS MATERIAL SAFETY DATA SHEET HAS BEEN PREPARED I/A/W
  APPLICABLE RIGHT-TO-KNOW REGULATIONS.
Federal Regulatory Information: PROD STATUS RELATIVE TO THE US EPA TOXIC
  SUBSTANCES CONTROL ACT: ALL CHEMICALSUBSTANCES IN THIS PROD ARE LISTED ON
  THE US TSCA INVENTORY OR ARE OTHERWISE EXEMPT FROM TSCA INVENTORY REPORTING
  REQUIRE MENTS.
State Regulatory Information: WARNING: THIS PRODUCT CONTAINS A CHEMICAL KNOWN
  TO THE STATE OF CALIFORNIA TO CAUSE CANCER.
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Other Information 
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Other Information: OTHER PROT EQUIP: CONT W/THIS PROD. FOR FREQUENT CONT/TOTAL
  IMMERSION, CONT MFR OF PROT CLTHG FOR APPROP CHEM IMPERVIOUS EQUIP. HAZ
  DECOMP PRODS: FLAME CUTTING, BRAZING, & WELDING.RATING: HEALTH1*.
  FLAMMABILITY 1. REACTIVITY 0. NFPA RATING: HEALTH 1. FLAMMABILITY 1.
  INSTABILITY 0. RATING SYS: 0-MINIMAL, 1=SLGIHT, 2=MOD, 3=SERIOUS.
  4=SEV,*=CHRONIC EFTS. SAFE HNDLG OF THIS PROD REQS THAT OF T HE INFO ON MSDS
  BE EVALUATED FOR SPECIFIC WORK ENVIRONMENTS & CNDTNS OF USE.
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HAZCOM Label 
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Company Name: PPG INDUSTRIES INC
Street: ONE PPG PLACE
Label Required IND: Y
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: INGEST: HARMFUL. EYE & SKIN: CAUSES IRRIT.
  INHAL: MAY BE HARMFUL. SIGNS & SYMPS OF OVEREXPOS: REDNESS, ITCHING,
  BURNING SENSATION & VISUAL DISTURB OF EYES. DRYNESS, ITCHING, CRACKING,
  BURNING,  REDNESS, & SWELL OF SKIN. CHRONIC: CANCER HAZ. CONTAINS SILICA,
  CRYSTALLINE-QUARTZ WHICH IS LISTED AS A HUMAN LUNG CARCINOGEN (FP N). AVOID
  LONG-TERM & RPTD CONT. POSSIBLE SILICOSIS.  INGEST OF PRODS  CONTAINING
  ETHYLENE GLYCOL MAY DMG KIDNEY & LIVER AND CAUSE POSSIBLE BIRTH DEFECTS. 
  ANIMALS INHALING MASSIVE QTIES OF TITANIUM DIOXIDE DEVELOPED LUNG TUMORS. 
  STUDIES W/HUMANS INVOLVED IN MFR OF THIS  PIGMENT INDICATE NO INCR RISK OF
  CANCER.
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