Control Measures 
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Contractor Summary 
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Item Description Information 
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Ingredients 
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OSHA PEL: NONE
OSHA STEL: NONE
ACGIH TLV: NONE
ACGIH STEL: NONE
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OSHA PEL: NONE
OSHA STEL: NONE
ACGIH TLV: NONE
ACGIH STEL: NONE
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% low Wt: 7.
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% low Wt: 3.
% high Wt: 7.
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% low Wt: 1.
% high Wt: 5.
OSHA PEL: NONE
OSHA STEL: NONE
ACGIH TLV: NONE
ACGIH STEL: NONE
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% low Wt: 1.
% high Wt: 5.
OSHA PEL: NONE
OSHA STEL: NONE
ACGIH TLV: NONE
ACGIH STEL: NONE
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% low Wt: 1.
% high Wt: 5.
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% low Wt: 1.
% high Wt: 5.
ACGIH TLV: 5 MG/M3 (AS FE)
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% low Wt: 1.
% high Wt: 5.
OSHA PEL: NONE
OSHA STEL: NONE
ACGIH TLV: NONE
ACGIH STEL: NONE
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< Wt: 2.
Other REC Limits: SEE TOX SECTION.
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Health Hazards Data 
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE: MODERATE IRRITATION: SIGNS/SYMPTOMS CAN INCLUDE
  REDNESS, SWELLING, PAIN, TEARING, & HAZY VISION. SKIN: MILD IRRITATION
  (AFTER PROLONGED OR REPEATED CONTACT): SIGNS/SYMPTOMS CAN INCLUDE REDNESS, S
  WELLING, ITCHING. INHALATION: CENTRAL NERVOUS SYSTEM DEPRESSION:
  SIGNS/SYMPTOMS CAN INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
  SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS & UNCONSCIO USNESS.
  IRRITATION (UPPER RESPIRATORY): SIGNS/SYMPTOMS CAN INCLUDE SORENESS OF NOSE
  & THROAT, COUGHING & SNEEZING. WHILE THE FOLLOWING EFFECTS ARE
  ASSOCIATED WITH ONE OR MORE OF THE INDIVIDUAL INGREDI ENTS IN THIS PRODUCT
  (EFTS OF OVEREXPOS)
Signs And Symptions Of Overexposure: HLTH HAZ (CONT'D): & ARE REQUIRED TO
  BE INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD, THEY
  ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT: KIDNEY
  EFFECTS: SIGNS /SYMPTOMS CAN INCLUDE REDUCED URINE VOLUME, BLOOD IN URINE AND
  BACK PAIN. LIVER EFFECTS: SIGNS/SYMPTOMS CAN INCLUDE YELLOW SKIN (JAUNDICE)
  & TENDERNESS OF UPPER ABDOMEN. IF SWALLOWED: INGESTION MAY CA USE:
  IRRITATION OF GASTROINTESTINAL TISSUES: SIGNS/SYMPTOMS CAN INCLUDE PAIN,
  VOMITING, ABDOMINAL TENDERNESS, NAUSEA, BLOOD IN VOMITUS, & BLOOD IN
  FECES. WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WIT H ONE OR MORE OF THE 
  (STATE REGULATORY)
First Aid: EYE CONTACT: IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER. GET
  IMMEDIATE MEDICAL ATTENTION. SKIN CONTACT: FLUSH SKIN WITH LARGE AMOUNTS OF
  WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. I NHALATION: REMOVE
  PERSON TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
  BREATHING IS DIFFICULT, GET IMMEDIATE MEDICAL ATTENTION. INGESTION: IF
  SWALLOWED, CALL A PHYSICIAN IMMEDIATELY.  ONLY INDUCE VOMITING AT THE
  INSTRUCTION OF A PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
  PERSON.
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Handling and Disposal
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Spill Release Procedures: REFER TO OTHER SECTIONS OF THIS MSDS FOR INFORMATION
  REGARDING PHYSICAL AND HEALTH HAZARDS, RESPIRATORY PROTECTION, VENTILATION,
  AND PERSONAL PROTECTIVE EQUIPMENT. VENTILATE AREA. EXTINGUISH ALL IGNIT ION
  SOURCES. COVER WITH ABSORBENT MATERIAL. COLLECT USING NON-SPARKING TOOLS.
  PLACE IN A U.S. DOT-APPROVED CONTAINER.
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL,
  STATE AND LOCAL REGULATIONS (FP N). INCINERATE IN A PERMITTED HAZARDOUS WASTE
  INCINERATOR IN THE PRESENCE OF A COMBUSTIBLE MATERIAL. DISPOSE OF WASTE 
  PRODUCT IN A FACILITY PERMITTED TO ACCEPT CHEMICAL WASTE.
Handling And Storage Precautions: AVOID EYE CONTACT. AVOID SKIN CONTACT. USE IN
  A WELL-VENTILATED AREA. AVOID PROLONGED BREATHING OF VAPORS. DO NOT INGEST.
  KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP AWAY FROM HEAT, OPEN FLAME, AND
  OT HER SOURCES OF IGNITION. GROUND CONTAINERS SECURELY WHEN TRANSFERRING
  CONTENTS.KEEP (OTHER PREC)
  HANDLING THIS MATERIAL.  KEEP CONTAINER TIGHTLY CLOSED. LOW STATIC OR
  PROPERLY GROUNDED SHOES. KEEP OUT OF THE REACH OF CHILDREN
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Fire and Explosion Hazard Information 
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Autoignition Temp Text: N/D
Lower Limits: CA. 1.4%
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: WEAR FULL PROTECTIVE CLOTHING, INCLUDING HELMET,
  NIOSH APPROVED (FP N) SELF-CONTAINED POSITIVE PRESSURE OR PRESSURE DEMAND
  BREATHING APPARATUS, BUNKER COAT AND PANTS, BANDS AROUND ARMS, WAIST AND LEGS
  , FACE MASK, AND PROTECTIVE COVERING FOR EXPOSED AREAS OF THE HEAD.
Unusual Fire/Explosion Hazard: CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY
  BUILD PRESSURE & EXPLODE. VAPORS MAY TRAVEL LONG DISTANCES ALONG GROUND
  OR FLOOR TO IGNITION SOURCE & FLASH BACK. FLAMMABLE LIQUID. KEEP
  CONTAINER TIGHT LY CLOSED. NFPA HAZARD CODES: HEALTH-2, FIRE-3, REACTIVITY-0.
  UNUSUAL REACTION HAZARD: NONE. FLAMMABLE LIQUID & VAPOR.
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Respiratory Protection: SELECT ONE OF THE FOLLOWING NIOSH APPROVED RESPIRATORS
  BASED ON AIRBORNE CONCENTRATION OF CONTAMINANTS AND IN ACCORDANCE WITH OSHA
  REGULATIONS: HALF-MASK ORGANIC VAPOR RESPIRATOR.
Ventilation: SUFFICIENT VENTILATION TO MAINTAIN EMISSIONS BELOW RECOMMENDED
  EXPOSURE LIMITS. IF EXHAUST VENTIALTION IS NOT ADEQUATE, USE APPROPRIATE
  REPIRATORY PROTECTION.
  (SUPP SFTY)
Other Protective Equipment: EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN
  CRITERIA (FP N).
  GLASSES WITH SIDESHIELDS. (MFR)
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Physical/Chemical Properties 
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M.P/F.P Text: N/D
Vapor Density: 2.5 AIR=1.
PH: N/D
Evaporation Rate & Reference: CA. 2.7.   WATER=1.
Solubility in Water: SLIGHT.
Appearance and Odor: REDDISH-BROWN, HEAVY SYRUP - KETONE ODOR.
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Reactivity Data 
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Stability Indicator: YES
Stability Condition To Avoid: STABLE.
Materials To Avoid: STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: CARBON MONOXIDE AND CARBON DIOXIDE, OXIDES OF
  NITROGEN, HYDROGEN CYANIDE, ALDEHYDES, KETONES, HYDROCARBONS, OXIDES OF ZINC.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information 
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Toxicological Information: EXPOSURE LIMITS: ZINC OXIDE (AS FUME): ACGIH TWA=5
  MG/M3. OSHA TWA=5 MG/M3.   NO SUBSTANCES OF THIS MATERIAL ARE POTENTIAL
  CONTRIBUTORS TO THE OVERALL EXPOSURE BY THE CUTANEOUS ROUTE INCLUDING MUCOUS 
  MEMBRANE AND EYE., EITHER BY AIRBORNE OR, MORE PARTICULARLY, BY DIRECT
  CONTACT WITH THE SUBSTANCE. VEHICLES CAN ALTER SKIN ABSORPTION.
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Ecological Information 
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Ecological: NOT DETERMINED.
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Regulatory Information 
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Sara Title III Information: THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS
  PHOSPHATE, AND ZINC OXIDE.
  REGULATIONS VARY, CONSULT APPLICABLE REGULATIONS OR AUTHORITIES BEFORE
  CLASS: FIRE HAZARD: YES. PRESSURE: NO. REACTIVITY: NO. ACUTE: YES. CHRONIC:
  YES.
State Regulatory Information: N/P. SIGNS/SYMPS OF OVEREXPOSURE (CONT'D):
  INDIVIDUAL INGREDIENTS IN THIS PRODUCT & ARE REQUIRED TO BE INCLUDED ON
  THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD, THEY ARE NOT
  EXPECTED EFFECT S DURING FORESEEABLE USE OF THIS PRODUCT. INGESTION MAY
  CAUSE: CENTRAL NERVOUS SYSTEM DEPRESSION: SIGNS/SYMPS CAN INCLUDE HEADACHE,
  DIZZINESS, DROWSINESS, MUSCULAR WEAKNESS, INCOORDINATION, SLOWED REA CTION
  TIME, FATIGUE, BLURRED VISION, SLURRED SPEECH, GIDDINESS TREMORS &
  CONVULSIONS. ASPIRATION PNE UMONITIS: SIGNS/SYMPS CAN INCLUDE COUGHING,
  DIFFICULTY BREATHING, WHEEZING, COUGHING UP BLOOD, & PNEUMONIA, WHICH CAN
  BE FATAL.
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Other Information 
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HAZCOM Label 
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Company Name: MINNESOTA MINING & MFG CO INDUSTRIAL TAPE & SPECIALTIES
  DIV
Street: 3M CENTER
Label Required IND: Y
Status Code: A
Origination Code: G
Hazard And Precautions: EYE: MODERATE IRRITATION: SIGNS/SYMPTOMS CAN INCLUDE
  REDNESS, SWELLING, PAIN, TEARING, & HAZY VISION. SKIN: MILD IRRITATION
  (AFTER PROLONGED OR REPEATED CONTACT): SIGNS/SYMPTOMS CAN INCLUDE REDNESS, S
  WELLING, ITCHING. INHALATION: CENTRAL NERVOUS SYSTEM DEPRESSION:
  SIGNS/SYMPTOMS CAN INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
  SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS & UNCONSCIO USNESS.
  IRRITATION (UPPER RESPIRATORY): SIGNS/SYMPTOMS CAN INCLUDE SORENESS OF NOSE
  & THROAT, COUGHING & SNEEZING. WHILE THE FOLLOWING EFFECTS ARE
  ASSOCIATED WITH ONE OR MORE OF THE INDIVIDUAL INGREDI ENTS IN THIS PRODUCT
  (EFTS OF OVEREXPOS)
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